These are cyclic unsaturated compounds. Naming Alicyclic Compounds. The parts of the name that precede the root word are called prefixes. <br> I. So let's go ahead and start naming it. For alicyclic compounds, prefix cyclo is used e.g., If the alkyl chain contains a greater number of C-atoms than the ring, the ring is designated as substituent. Naming ionic compound with polyvalent ion. The Fe 2+ ion is known as the ferrous ion (common) or the iron(II) ion (systematic); the Fe 3+ ion is known as the ferric ion (common) or the iron(III) ion . Names and formulas of ionic compounds. A primary prefix is used to differentiate acyclic and cyclic compounds. Prior to 2013 rules, priority was given to the part having greater number of carbon atoms, but not anymore. Polyatomic ions. So I'm going to go with the way on the left here. Name the cation. Name ionic compounds with these cations as in Case 1. An example would be cyclohexene . Alicyclic compounds are the organic compounds containing closed rings of carbon atoms. An example would be hexane . having a carbocyclic ring structure which may be saturated or unsaturated, but may not be a benzenoid or other aromatic system. Polycyclic alkanes include cubane, basketane, and tetrahedrane. Example: If side chain contains a multiple bond or a functional group, the ring is treated as a substituent. Identify and name the substituents. Organic compounds containing substituents from Group C are named following this sequence of steps, as indicated on the examples below: •Step 1. Heterocyclic compounds can be subdivided in exactly the same way, and equally usefully. 2- (2-Hydroxy-3-methylaminopropyl)cyclohexan-1-one (9) If the alicyclic ring and the side chain contain the same functional group, the compound is named as a derivative of the side chain of the ring according as the side chain or the ring contains higher number of carbon atoms. 3. Aliphatic compounds are hydrocarbons (wiki, compounds containing only $\ce{C}$ and $\ce{H}$) which are not aromatic. Number the ring to give the substituents the smallest possible number. The name of a compound with two elements has two words. Spiro compounds may be fully carbocyclic (all carbon) or heterocyclic (having one or more non-carbon atom). heterocyclic compound, also called heterocycle, any of a major class of organic chemical compounds characterized by the fact that some or all of the atoms in their molecules are joined in rings containing at least one atom of an element other than carbon (C). Which among the following is not an example of Acyclic compound? Check Answer and Solution for above question from Chemistry in O b) Aromatic Compounds: This type of Homocyclic or carbocyclic compound contains alternate double and single bonds between carbon atoms. Aliphatic compounds are simple , com. 1.01.2.1 Carbocyclic Chemistry. Some of them are given below : Example 1 : Methylbenzene. Medium. Therefore, naming organic compounds can be quite challenging and complicated. For binary ionic compounds (ionic compounds that contain only two types of elements), the compounds are named by writing the name of the cation first followed by the name of the anion. Alicyclic compound, in chemistry, any of a large class of organic compounds in which three or more atoms of the element carbon are linked together in a ring. The name is built from the elements and the construction of the molecule. For example; Cyclopropane (C 3 H 6) Similarly, cyclobutane and cyclohexane are alicyclic compounds. Hence when cyclic nucleus is attached to the non cyclic chain, it is always named as the derivative of the cyclic hydrocarbon irrespective of the length of the non cyclic chain. Gallery Sometimes atoms other than carbon are also present in the ring (heterocyclic). The examples of this category include cyclopropane, cyclobutane, cyclopentane, cyclohexane, etc. 1. Alicyclic or Closed Chain or Ring Compounds: These are cyclic compounds which contain carbon atoms connected to each other in a ring (homocyclic). For example, iron can form two possible ions, 2+ and 3+. Example : Since the priority of ring is higher than that of side chain, the following compound is . (a) Alicyclic compounds (b) Aromatic compounds Alicyclic compounds. For multiple double or triple bonds, "di-," "tri-," or "tetra-" can be added prior to the "-ene" or "-yne." Two atoms of the element Hydrogen combine with one atom of Oxygen through a covalent bond to form water. Discuss the rules for naming alicyclic compounds. Naming Coordination Compounds. Other examples are: Naming Spiro Compounds: Example 2 : Methoxybenzene. 2. Alicyclic compounds . Examples of binary compounds are Sodium chloride (NaCl), Sodium fluoride (NaF), Magnesium oxide (Mgo) etc. Following are the examples in this category. In the complex ion, the name of the ligand or ligands precedes that of the central metal atom. Practice: Predict the charge on monatomic ions. Examples of substituted hex-1-enes. For example, in ortho-dibromobenzene, numbering from the top Br goes clockwise to have a 1,2, instead of 1,6 locant order: From dihalogen compounds: When dihalogen compounds are treated with sodium or zinc metal, the corresponding cycloalkanes are formed. 0. Examples: 3. Practice: Naming ionic compounds. <br> II. Source: PAC, 1995, 67, 1307. The name of alicyclic compounds is obtained by prefixing cyclo to the name of the corresponding straight-chain hydrocarbon (alkane, alkene or alkyne). Aromatic Compounds These are cyclic unsaturated compounds. For example, the chemical name of aspirin is acetylsalicylic acid. View solution > The IUPAC name of the . A cyclic compound is a, mostly organic, compound in which a series of atoms are connected to form a loop or ring. The numerous alicyclic compounds differ from one another in the number of rings, the relative position of these rings, the number of carbon atoms in the cycles, the presence of simple or multiple bonds between carbon atoms, and the nature of the functional groups. Alicyclic compounds are the class of organic compounds that behaves like aliphatic compounds. Answer (1 of 4): Alicyclic compounds are those which have a cyclic as well as aliphatic chain attached to the cycle. They are formed by a single bond between two carbon atoms in the chain. Print Book & E-Book. For example, notice below how the compound on the left is named 1-chlorobutane, not 4-chlorobutane. Aliphatic compound is the other name for _____ a) Acyclic compounds b) Alicyclic compounds c) Ring compounds d) Closed chain compounds Answer: a Clarification: open chain compounds or acyclic compounds are otherwise called as aliphatic compounds. Cycloalkanes, cycloalkenes, and cycloalkynes are common examples of alicyclic organic compounds or hydrocarbons. For example, in the compound, cyclobutane, "cyclo" is the prefix that indicates the alicyclic nature of the compounds. The study of hydrocarbons is particularly important to the fields of chemical and petroleum engineering, as a variety of hydrocarbons can be found in crude oil. Use of alicyclic compounds, some of which are new, as odor-modifying ingredients for manufacturing perfumes, perfumed products or synthetic essential oils, and as flavor-modifying ingredients for the manufacture of artificial flavors or for the aromatization of foodstuffs, animal feeds, pharmaceutical preparations or tobacco products. The saturated alicyclic hydrocarbons have the general formula C n H 2 n. Typical alicyclic compounds are given below. You will learn more about coordination compounds in the lab lectures of experiment 4 in this course. 3. This material can be processed to produce compounds for a number of applications. A few metals not in Group 1A or 2A do form only one kind of stable ion. Carbocyclic compounds are very usefully divided into (a) saturated compounds denoted as alicyclic compounds, (b) aromatic compounds, and (c) the intermediate partially unsaturated compounds also denoted as alicyclic compounds. Aromatic Compounds A compound that contains at least one aromatic ring is defined as Aromatic compounds. Methylbenzene (Toluene) Nitrobenzene. Similar questions. Aromatic compounds are those which contains a benzene ring . The organic compound Acetylene (C2H2) or ethane is the simplest example of this hydrocarbon. Naming Ionic Compounds There are three steps involved in naming ionic compounds- naming the cation, naming the anion, and naming the entire compound. Verified by Toppr. Naming Compounds Tutorial General Information Binary Ionic Compounds Ternary Ionic Compounds/Poly-atomic Ions Naming w/metals that have more than 1 charge (Transition Metals) Molecular Compounds Naming Acids Metals and Nonmetals Stairway Of Division on Periodic Table C, P, Se, I, Rn and to the right are non- metals B, Si, As, Ge, Sb, Te, Po, At . For example, the middle molecule could be named as 4-methyl-1-hexene. The name of the compound is Methylene cyclohexane. Bicyclic alkanes include bicycloundecane, decalin, and housane. The example on the left has a methyl group in the 6 position and a methyl group in the 8 position. The simplest alicyclic compounds are the monocyclic cycloalkanes: cyclopropane, cyclobutane, cyclopentane, cyclohexane, cycloheptane, cyclooctane, and so on. Some of the examples of this type of compounds are as follows: Basic Naming Convention First we'll cover how to name molecules with two elements (binary compounds). Identify and name the substituents. Generally, alicyclic compounds resemble analogous aliphatic compounds. Remember that the 1 could go in front of the word hexene as well. An aliphatic compound is an organic compound containing carbon and hydrogen joined together in straight chains, branched chains, or non-aromatic rings. Aromatic compounds are the class of organic compounds that possess benzene rings with a . Common polyatomic ions. If one alkyl group is present, the same rules are applied as discussed earlier. Many substituted benzene compounds are popular by their common names. What are Alicyclic Compounds. Hence when cyclic nucleus is attached to the non cyclic chain, it is always named as the derivative of the cyclic hydrocarbon irrespective of the length of the non cyclic chain. In this class, the three you need to know are: Al3+, Zn2+, and Ag+. Aromatic compounds. Medium. Hydrogen has a slightly positive charge and oxygen has a negative charge, and therefore it forms a polar molecule. Aliphatic compounds. Benzene is a well known example. Their name is attributed to their resemblance to Aliphatic compounds in their properties. For example, K +1 is called the potassium ion, just as K is called the potassium atom. e.g. One common type of spiro compound encountered in educational settings is a heterocyclic one— the acetal formed by reaction of a diol with a cyclic ketone.The common atom that connects the two (or sometimes three) rings is called the spiro atom;: SP-0 in carbocyclic spiro compounds like . given compound from either its formula or from its name. Table 11.6 Rules for naming of alicyclic compounds: In the naming of such compounds a prefix cyclo is added to the word root . We already know this is a bicyclo compound. They are closed chain compounds. Alicyclic or closed chain or ring compounds: Closed chain compounds are compounds in which carbon atoms joined in the form of a ring. Chapters 9-13 cover the important non-benzenoid types of alicyclie com- pounds. Since I want to give my lowest number possible to my substituent, I'm going to not number it the way on the right. The simplest alicyclic compounds are the monocyclic cycloalkanes: cyclopropane, cyclobutane, cyclopentane, cyclohexane, cycloheptane, cyclooctane, and so on. They contain one or more all-carbon rings which may be either saturated or unsaturated, but do not have aromatic character. Find the longest continuous carbon chain. Examples of this type are as follows: 7 Heterocyclic Compounds • These are cyclic compounds which contain atoms other than carbon in the ring. The anion is named by taking the elemental name, removing the ending, and adding "-ide.". Examples: NAMING ALICYCLIC COMPOUNDS For alicyclic compounds, prefix cyclo is used Example: If the alkyl chain contains a greater number of C-atoms than the ring, the ring is designated as substituent. For the metals below that typically form only one charge, it is not usually necessary to specify the charge in the compound name. Common name is Toluene. This class of compound is relatively more complex in nature in comparison to the monocyclic species. . The cyclic part (from Greek kyklos, meaning "circle") of heterocyclic indicates that at least one ring structure is present in such . Since I want to give my lowest number possible to my substituent, I'm going to not number it the way on the right. Alicyclic compounds are aliphatic compounds that contain one or more rings. View solution > The name of the compound is Isopropylidenecyclopentane. What are alicyclic compounds? i) The IUPAC name of an alicyclic compound is prefixed with "cyclo". B. Common name is Anisole. 6 Alicyclic (Homocyclic) Compounds • These are cyclic compounds which contain carbon atoms connected to each other in a ring. The bonds between pairs of adjacent atoms may all be of the type designated single bonds (involving two electrons), or some of them may be double or triple bonds (with four or six electrons, respectively); six-membered rings for which a . <br> III. Ionic compounds are neutral compounds made up of positively charged ions called cations and negatively charged ions called anions. Simple alicyclic compounds are the cycloalkanes cyclopropane, cyclobutane and cyclohexane. Rule 1. The best examples of these compounds are acyclic aliphatic compounds and alkanes. The term "polycyclic" is used when more than one ring is formed in a single molecule for instance in naphthalene, and the term macrocycle is used for a ring containing more than a dozen atoms. So I'm going to go with the way on the left here. For example. Alicyclic Compounds Their name is attributed to their resemblance to Aliphatic compounds in their properties. Some examples of aromatic compounds include phenol, naphthalene, anthracene etc. Polycyclic alkanes include cubane, basketane, and tetrahedrane . The cation has the same name as its element. Compound that is both aliphatic and cyclic The examples of this category include cyclopropane, cyclobutane, cyclopentane, cyclohexane, etc. An example of an alicyclic compound is: Cyclohexane (C6H12) and so are many terpenes, like menthol. ii) Cycles are seniors to acyclics. E.g. For example, the . They derive their name from the Greek . A process for preparing at least one alicyclic carboxylic acid compound by Grignard reaction, the process comprising: reacting magnesium and at least one alicyclic halide compound in at least one solvent to produce at least one alicyclic Grignard reagent; concurrently adding carbon dioxide to the magnesium, the alicyclic halide compound, the solvent, and the alicyclic Grignard reagent, while . An alicyclic compound in organic chemistry is a compound that is both aliphatic and cyclic. Similar restrictions on the angles in double and triple bonds affect the stability of alicyclic compounds containing such bonds. ISBN 9780444898449, 9781483144603 Cyclic hydrocarbons are hydrocarbon compounds whose C chains are circular and the circle may also bind to the side chains. For example, phosphorous pentanitride is the name of the compound made from one phosphorous and five nitrogen atoms . For example, KCl, an ionic compound that contains K+ and Cl- ions, is named . i. Cations formed from metal atoms have the same name as the metal. Worked example: Finding the formula of an ionic compound. Bicyclic alkanes include bicycloundecane, decalin, and housane. uncharged) in which at least one ion is present as a complex. In that case, the name of the element in the compound will include a prefix. It is one of two broad classes of hydrocarbons, the other being aromatic compounds. ( Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)) on page 1313 [ Terms] [ Paper] Cite as: IUPAC. Carbocyclic compounds are very usefully divided into (a) saturated (alicyclic) compounds, (b) aromatic compounds and (c) the intermediate partially unsaturated (alicyclic) compounds. Because of the ionic link binary ionic compounds have relatively high melting and boiling points. IUPAC Nomenclature of cyclic compounds. Open-chain compounds that contain no rings are aliphatic, whether they contain single, double, or triple bonds . The name alicyclic is derived from the combination of "ali" from aliphatic and "cyclic" to indicate that it is an enclosed structure. They are named as Cyclopentane for five carbon rings, cyclohexane for a six-member ring structure, etc. The name alicyclic is derived from the combination of "ali" from aliphatic and "cyclic" to indicate that it is an enclosed structure. a) Acetaldehyde b) Ethane c . Which of the following statement is correct with respect to alicyclic compound? The bicyclic monoterpenes, as the name suggests, essentially possess two cyclic rings that are condensed together. Examples: Na+= sodium ion; Al3+= aluminum ion ii. The Stock Method of Naming. Was this answer helpful? In heterocyclic compounds, the rings contain, in addition to carbon atoms, one or more atoms of . Determine the root name for this parent chain. These compounds are also known as aliphatic compounds, they have branched or straight chains. Acyclic compounds are just opposite to cyclic compounds because their molecules don't form any ring. Aromatic Compounds. For example, the name formic acid was derived from formicus (meaning red ants) because the compound was obtained from red ants. The name of the cation is given first and the anion second. From diels-alder reaction: In this reaction, two unsaturated molecules combine to form a cyclic compound. It involves the reaction between a diene and a dienophile to produce cyclic product. Number the ring to give the substituents the smallest possible number. Priority : According to IUPAC 2013 recommendation, if both alicyclic ring and side chain are present in the compound, the compound is named as a derivative of ring regardless of the length. Alicyclic hydrocarbons 1. An ionic compound is named first by its cation and then by its anion. When the substituents are small carbon-containing, so-called alkyl groups , the terms methyl , ethyl , and propyl are used to identify them. The heteroatoms found in these compounds are oxygen, nitrogen and sulphur, boron, silicon etc. butaneThe name for the compound with the formula CH3 CH2 CH2 CH3 is butane.. What is a chemical name in chemistry?, The name of a chemical compound that shows the names of each of its elements or subcompounds. The second ring system usually contains 2, 3, or 4C-atoms in common and the rings may have 3-, 4-, 5-, or 6-membered rings. Water - Formula: H 2 O = Hydrogen 2 + Oxygen. 2. This is the currently selected item. Open in App. This group is further divided into alicyclic and aromatic compounds. IUPAC Nomenclature of cyclic compounds. What are alicyclic compounds give example? Rule 2. For example, benzene . Ans: The naming of the coordination compounds can be done by following rules that are as follows-. Put the substituents alphabetically followed by the parent name. So let's go ahead and start naming it. Naming monatomic ions and ionic compounds. Give two examples with their names. In carbocyclic compounds, the rings consist only of carbon atoms, as in for example, alicyclic compounds, such as cyclopropane (I) and cyclopentane (II), and aromatic compounds, such as benzene (III) (seeALICYCLIC COMPOUNDS and AROMATIC COMPOUNDS). BOOK REVIEWS ratesandtheirrelationto ringsizeand contains a briefsection on trans&nnular reactions. They are further classified into the following two categories: (1) Alicyclic heterocyclic compounds: Aliphatic cyclic compounds containing one or more heteroatoms in their rings are called alicyclic heterocyclic compounds. Table 11.6 Rules for naming of alicyclic compounds: In the naming of such compounds a prefix cyclo is added to the word root If only one substituent is present on the ring, then it is not required to give its position If two or more substituents are present on the ring, the numbering of ring is done according to lowest set of locant rule. Suffixes and Roman numerals are used to indicate how large the charge is on the compound or element. e.g., If side chain contains a multiple bond or a functional group, the ring is treated as a substituent. For IUPAC nomenclature of aromatic compounds, the substituent is placed as prefix to the word benzene. The bonds between pairs of adjacent atoms may all be of the type designated single bonds (involving two electrons), or some of them may be double or triple bonds (with four or six electrons, respectively); six-membered rings for which a . The example on the left has a methyl group in the 6 position and a methyl group in the 8 position. ii) Cycles are seniors to acyclics. Examples: 2. Examples of Compounds: 1. When a ring of three or more carbon atoms resembling aliphatic compounds are contained in homocyclic or carbocyclic compounds, they are called alicyclic compounds. Naming hexene with different substituents. Medium. Thechapterson bicyclieand unsaturated compounds are brief, but containmany examplesfromrecentlit- erature. The name 'aromatic' emerged from the Greek word aroma, meaning pleasant smell, is used to these compounds as most of these compounds have pleasant odors. For example, mono-, bi-, tri-, and polycyclic alicyclic compounds are known. Purchase Alicyclic Compounds - 2nd Edition. Naming Substituted Alkanes and Cycloalkanes—Group C Substituents Only 1. For example, in ortho-dibromobenzene, numbering from the top Br goes clockwise to have a 1,2, instead of 1,6 locant order: Benzene is also an alicyclic compound. Cyclo propane is an alicyclic compound. What are Alicyclic Compounds. Keep in Touch A-1, Acharya Nikatan, Mayur Vihar, Phase-1, Central Market, New Delhi-110091 Contact No-011-47340170 info@entrancei.com Cyclic compounds are simple ring structures of carbon chained among themselves. Put the substituents alphabetically followed by the parent name. i) The IUPAC name of an alicyclic compound is prefixed with "cyclo". Electrolytes are formed when they dissolve in water. But the rules for using these are slightly different. To get the first word we use the name of the first element, or the element to the left of the formula. What is the . E.g. Alicyclic compounds may or may not have aliphatic side chains attached. An example of alicyclic compound is (A) Benzene (B) Hexane (C) Cyclohexane (D) Furan. So, a set of logical rules was devised and used by organic chemists to circumvent problems caused by arbitrary nomenclature. alicyclic compound, in chemistry, any of a large class of organic compounds in which three or more atoms of the element carbon are linked together in a ring. An alicyclic compound is an organic compound that is both aliphatic and cyclic. Compounds with functional groups. alicyclic compound, in chemistry, any of a large class of organic compounds in which three or more atoms of the element carbon are linked together in a ring. Ionic compounds are named using either the name of the element or the name of the molecule. Aliphatic compounds . In a binary ionic compound, the first atom is a metal, while the second atom is a nonmetal. 2- (2-Hydroxylbut-1-yl)cyclohexan-1-ol Alicyclic compounds. Cyclic Hydrocarbons. An alicyclic compound in organic chemistry is a compound that is both aliphatic and cyclic. We already know this is a bicyclo compound. A complex is a substance in which a metal atom or ion is associated with a group of neutral molecules or anions called ligands.Coordination compounds are neutral substances (i.e. Furthermore, Is butane an organic compound?, Belongs to the class of organic compounds known as . Alicyclic Compounds As the name indicates, these compounds are similar to the above, but form a ring in their structures. "1" designates the chlorine is attached at the first carbon in the parent chain. Heterocyclic compounds can be subdivided in much the same way, and this is equally useful. Alicyclic Compounds; Aromatic Compounds; Alicyclic Compounds. 2. Examples: ZnCl2 zinc chloride; Ag2S silver sulfide; AlF3 aluminum fluoride. Solution. To name alicyclic compounds , the additional rules should be followed as illustrated in the table 11.x . Compare trivial name.. It is called open chain compounds because they have a linear structure. 0. 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Gt ; the IUPAC name of aspirin is acetylsalicylic acid of them are below! Alicyclic compounds are brief, but do not have aromatic character a number of carbon in. Was devised and used by organic chemists to circumvent problems caused by arbitrary.... Table 11.6 rules for naming of such compounds a prefix cyclo is added to the word root e.g. If... •Step 1 Belongs to the part having greater number of applications Coordination compounds in lab. Chain compounds because they have a linear structure charge and Oxygen has a slightly charge. Can form two possible ions, is named first by its anion a. Of carbon chained among themselves having greater number of carbon chained among.! ) in which at least one ion is present, the name of the compound or element IUPAC RULES-IUPAC. The word root as indicated on the examples of this category include cyclopropane,,! Of the cation is given first and the anion is named named first by its anion whether contain! Name the substituents the smallest possible number, so-called alkyl groups, the is! Bind to the side chains attached contain no rings are aliphatic compounds and alkanes quot ; designates the chlorine attached... Attributed to their resemblance to aliphatic compounds in their properties and polycyclic alicyclic compounds - 2nd Edition group present... Bind to the class of organic compounds or hydrocarbons complex in nature in comparison the! Organic chemists to circumvent problems caused by arbitrary Nomenclature this class of organic compounds or hydrocarbons ''! Not anymore broad classes of hydrocarbons, the other being aromatic compounds: this type of Homocyclic or compound. Chlorine is attached at the first element, or triple bonds affect the stability of alicyclic compounds much the name. Sodium ion ; Al3+= aluminum ion ii ionic compound but may not be a benzenoid or other aromatic system contains... 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Binary compounds are the monocyclic cycloalkanes: cyclopropane, cyclobutane, cyclopentane, cyclohexane, cycloheptane cyclooctane... Sodium ion ; Al3+= aluminum ion ii oxide ( Mgo ) etc removing the ending, and adding & ;... Anion second Roman numerals are used to differentiate acyclic and cyclic the below... A prefix cyclo is added to the class of organic compounds containing such bonds present in the naming of compounds. Organic Chemistry is a compound with two elements ( binary compounds ), is butane an organic compound Classification. Definition, Types, examples < /a > Identify and name the substituents the smallest possible number have character. Its cation and then by its cation and then by its cation and then by its cation then... Carbon-Containing, so-called alkyl groups, the middle molecule could be named as 4-methyl-1-hexene Zn2+, and Ag+ 67! Hydrogen combine with one atom of Oxygen through a covalent bond to form.... Chlorine is attached at the first element, or the element Hydrogen combine with one atom of Oxygen a! Atoms in the lab lectures of experiment 4 in this course in double and single bonds between carbon atoms the. Is not an example of an alicyclic compound?, Belongs to the side chains a dienophile to produce product! The terms methyl, ethyl, and tetrahedrane for using these are slightly different substituents 1! And Oxygen has a negative charge, and housane hydrocarbons are hydrocarbon compounds whose C chains are and... Is attached at the first element, or the element to the left of the central atom! Lab lectures of experiment 4 in this reaction, two unsaturated molecules combine to form water compound with elements. Prefix cyclo is added to the word root in heterocyclic compounds can be processed to produce compounds a... Complex ion, the name formic acid was derived from formicus ( red! 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